World Library  

QR link for The Journal of Chemical Physics : Rovibrational matrix elements of the quadrupole moment of N2 in a solid parahydrogen matrix
Add to Book Shelf
Flag as Inappropriate
Email this Book

The Journal of Chemical Physics : Rovibrational matrix elements of the quadrupole moment of N2 in a solid parahydrogen matrix

By Adya P. Mishra and T. K. Balasubramanian

Click here to view

Book Id: WPLBN0002169505
Format Type: PDF eBook :
File Size: Serial Publication
Reproduction Date: 18 November 2008

Title: The Journal of Chemical Physics : Rovibrational matrix elements of the quadrupole moment of N2 in a solid parahydrogen matrix  
Author: Adya P. Mishra and T. K. Balasubramanian
Volume: Issue : November 2008
Language: English
Subject: Science, Physics, Natural Science
Collections: Periodicals: Journal and Magazine Collection (Contemporary), The Journal of Chemical Physics Collection
Historic
Publication Date:
Publisher: American Institute of Physics

Citation

APA MLA Chicago

Mishra And T. K. Balasubramania, A. P. (n.d.). The Journal of Chemical Physics : Rovibrational matrix elements of the quadrupole moment of N2 in a solid parahydrogen matrix. Retrieved from http://community.worldlibrary.net/


Description
Description: The present work pertains to the study of the rotational dynamics of N2 molecules solvated in a matrix of solid para-H2. It is shown that the mixing of the rotational states due to the anisotropic part of the N2–H2 pair potential in the solid gives rise to an additional 5.4% contribution to the intensity of quadrupole-induced double transitions involving N2–H2 pair. Hence the recently reported quadrupole moment matrix element of N2 in a solid para-H2 crystal [ A. P. Mishra and T. K. Balasubramanian, J. Chem. Phys. 125, 124507 (2006) ], which was deduced from a comparison of the theoretical intensity (with rotational mixing of states neglected) with the measured value is larger by ∼ 2.7%. The ground electronic state rovibrational matrix elements 〈v′J′|Q2(r)|vJ〉 of N2 molecule in a solid parahydrogen matrix for v,v′ ≤ 1 and J,J′ ≤ 4 have also been computed by taking into account the changes in the intramolecular potential of N2 due to the intermolecular interaction in the matrix. The computed quadrupole moment matrix elements agree well with a few available values (for v = v′ = 0) deduced from the observed transitions.

 

Click To View

Additional Books


  • Biblioteca Hispanica : a Natural History (by )
  • Applied Physics Letters : Multilayered s... Volume Issue : December 2008 (by )
  • Journal of Applied Physics : Optical and... Volume Issue : November 2008 (by )
  • Applied Physics Letters : Temperature di... Volume Issue : December 2008 (by )
  • Journal of Applied Physics : The influen... Volume Issue : November 2008 (by )
  • Applied Physics Letters : Reduced boron ... Volume Issue : December 2008 (by )
  • Biblioteca Hispanica : the Water on Eart... (by )
  • Applied Physics Letters : Scatterometry ... Volume Issue : December 2008 (by )
  • Physics of Plasmas : Modeling of an adva... Volume Issue : November 2008 (by )
  • Journal of Applied Physics : Phase trans... Volume Issue : November 2008 (by )
  • Applied Physics Letters : Enhanced and p... Volume Issue : December 2008 (by )
  • Journal of Applied Physics : Strain rela... Volume Issue : November 2008 (by )
Scroll Left
Scroll Right

 



Copyright © World Library Foundation. All rights reserved. eBooks from World Library are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.